Characterization of Foxing Stains by Chemical and Spectrometric Methods

Bibliographic Details
Main Authors: Bicchieri, Marina (Author), Pappalardo, Giuseppe (Author), Romano, Francesco Paolo (Author), Sementilli, Francesca Maria (Author), Acutis, Rodolfo De (Author)
Format: Article
Language:English
Slovak
ISSN:ISSN 0034-5806
Online Access:http://www.viks.sk/chk/res_1_01_1_19.doc
Description
Abstract:SUMMARIES. Foxing stains on six different papers from the 16th-18th centuries and additionally fox-like stains produced by dropping different amounts (1, 3 and 5 ul) of solutions of FeCl3, KCl and FeCl3+KCl (5.10-3 M) on modern paper and artificially ageing were analyzed for chromaticity, fluorescence under UV ilumination, carbonyl content, thickness and subumitted to IR spectroscopy and XRF spectrometry. As a result it is stated that the foxing phenomenon is related to a strong oxidation of the cellulose chain. Not regarding certain and possibly specific differences between different kinds of foxing stains, this strong oxidation is the only common characteristic for foxed areas.
ISSN:ISSN 0034-5806